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二溴{2-[(4-溴苯基)亚氨基甲基]吡啶-κN,N'}锌(II)

Dibromido{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).

作者信息

Khalaj Mehdi, Dehghanpour Saeed, Mahmoudi Ali, Seyedidarzam Shila

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2009 Jul 11;65(Pt 8):m890. doi: 10.1107/S1600536809025653.

DOI:10.1107/S1600536809025653
PMID:21583353
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2977329/
Abstract

In the title complex, [ZnBr(2)(C(12)H(9)BrN(2))], the Zn(II) ion is in a distorted tetra-hedral coordination environment formed by two imine N atoms of the bis-chelating N-heterocyclic ligand and two Br atoms. The dihedral angle between the pyridine and benzene rings is 8.04 (17)°.

摘要

在标题配合物[ZnBr₂(C₁₂H₉BrN₂)]中，Zn(II)离子处于由双螯合N-杂环配体的两个亚胺N原子和两个Br原子形成的扭曲四面体配位环境中。吡啶环和苯环之间的二面角为8.04 (17)°。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d34/2977329/d6e33f7092cd/e-65-0m890-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d34/2977329/d6e33f7092cd/e-65-0m890-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/2d34/2977329/d6e33f7092cd/e-65-0m890-fig1.jpg

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[二（2,6 - 二氯亚苄基）丙烷 - 1,3 - 二胺 - κ(2)N,N']二溴化锌
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Dibromido{2-[(4-nitro-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).二溴化{2-[(4-硝基苯基)亚氨基甲基]吡啶-κN,N'}锌(II)
Acta Crystallogr Sect E Struct Rep Online. 2011 Nov;67(Pt 11):m1556. doi: 10.1107/S1600536811042231. Epub 2011 Oct 22.