Xu Lingli, Huo Zhibao, Fu Jun, Jin Fangming
School of Environmental Science and Engineering, Shanghai Jiao Tong University, 800 Dongchuan Road, Shanghai 200240, China.
Chem Commun (Camb). 2014 Jun 7;50(45):6009-12. doi: 10.1039/c3cc49439j. Epub 2014 Apr 25.
The efficient conversion of biomass-derived glycolide into ethylene glycol over CuO in water was investigated. The reaction of glycolide was carried out with 25 mmol Zn and 6 mmol CuO with 25% water filling at 250 °C for 150 min, which yielded the desired ethylene glycol in 94% yield.
研究了在水中通过氧化铜将生物质衍生的乙交酯高效转化为乙二醇的过程。乙交酯的反应是在250℃下，用25 mmol锌和6 mmol氧化铜以及25%的水填充量进行150分钟，得到了产率为94%的目标乙二醇。
