通过铑催化的酰胺与 N-磺酰基-1,2,3-三唑的反应，从末端炔烃直接合成烯胺酮。
Direct production of enaminones from terminal alkynes via rhodium-catalyzed reaction of formamides with N-sulfonyl-1,2,3-triazoles.
机构信息
Department of Synthetic Chemistry and Biological Chemistry, Kyoto University , Katsura, Kyoto 615-8510, Japan.
出版信息
Org Lett. 2014 May 16;16(10):2760-3. doi: 10.1021/ol5010774. Epub 2014 Apr 28.
PMID:24773098
Abstract
A rhodium-catalyzed reaction of formamides with N-sulfonyl-1,2,3-triazoles is developed to formulate a new one-pot procedure for the direct synthesis of α-amino enaminones from terminal alkynes.
摘要
发展了一种铑催化的甲酰胺与 N-磺酰基-1,2,3-三唑的反应，建立了一种新的从末端炔烃直接合成α-氨基烯胺酮的一锅法反应。
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