Matsuoka Ryota, Sakamoto Ryota, Kambe Tetsuya, Takada Kenji, Kusamoto Tetsuro, Nishihara Hiroshi
Department of Chemistry, Graduate School of Science, The University of Tokyo, 7-3-1, Hongo, Bunkyo-ku, Tokyo 113-0033, Japan.
Chem Commun (Camb). 2014 Aug 4;50(60):8137-9. doi: 10.1039/c4cc02022g.
A liquid-liquid interfacial synthesis using 1,2,4,5-benzenetetrathiol and nickel(II) ions produced a thin black film of a π-conjugated polymer featuring the nickel bis(dithiolene) motif. Its ordered structure was not originally identified due to its amorphicity; however, it was observed to align regularly on a highly oriented pyrolytic graphite substrate using scanning tunnelling microscopy.
使用1,2,4,5-苯四硫醇和镍（II）离子进行的液-液界面合成产生了一种具有镍双（二硫烯） motif的π共轭聚合物黑色薄膜。由于其无定形性质，其有序结构最初未被识别；然而，使用扫描隧道显微镜观察到它在高度取向的热解石墨衬底上规则排列。
