通过硫醇-烯化学合成新型脂质启发的离子液体：溶剂对反应途径的深刻影响。
Synthesis of new lipid-inspired ionic liquids by thiol-ene chemistry: profound solvent effect on reaction pathway.
作者信息
Mirjafari Arsalan, O'Brien Richard A, West Kevin N, Davis James H
机构信息
Department of Chemistry and Physics, Florida Gulf Coast University, 10501 FGCU Blvd. S., Fort Myers, FL 33965 (USA).
出版信息
Chemistry. 2014 Jun 16;20(25):7576-80. doi: 10.1002/chem.201402863. Epub 2014 May 5.
The synthesis of a series of new lipid-inspired ionic liquids through thiol-ene "click" reaction with a single-step process. This synthesis offers considerable promise as an efficient and orthogonal method to construct structurally diverse imidazolium-type ionic liquids with linear and branched cationic tails, as well as versatility in the placement of the sulfur heteroatom. Profound solvent effect in this ene reaction regioselectivity has been observed.
通过硫醇-烯“点击”反应以一步法合成了一系列新型脂质启发的离子液体。这种合成方法作为一种有效且正交的方法，有望构建具有线性和支链阳离子尾部的结构多样的咪唑型离子液体，并且在硫杂原子的位置上具有通用性。已观察到该烯反应区域选择性中存在显著的溶剂效应。
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