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3,3'-二甲氧基联苯-4,4'-二甲酸二甲酯

Dimethyl 3,3'-di-meth-oxy-biphenyl-4,4'-di-carboxyl-ate.

作者信息

Lundvall Fredrik, Wragg David Stephen, Dietzel Pascal D C, Fjellvåg Helmer

机构信息

Centre for Materials Science and Nanotechnology, Department of Chemistry, University of Oslo, PO Box 1126, 0315 Oslo, Norway.

Centre for Materials Science and Nanotechnology, Department of Chemistry, University of Oslo, PO Box 1126, 0315 Oslo, Norway ; inGAP National Centre of Research-based Innovation, Department of Chemistry, University of Oslo, PO Box 1126, 0315 Oslo, Norway.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 Mar 15;70(Pt 4):o449. doi: 10.1107/S1600536814005613. eCollection 2014 Apr 1.

DOI:10.1107/S1600536814005613
PMID:24826151
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC3998533/
Abstract

In the title compound, C18H18O6, the biphenyl moiety is twisted with a dihedral angle of 29.11 (10)°. The carbometh-oxy groups form C-C-C-O torsion angles of -18.3 (3) and -27.7 (3)° with the attached rings, as a result of steric hindrances from the nearby meth-oxy groups. In the absence of stacking inter-actions and with no H⋯O contacts shorter than 2.7 Å, the packing is dominated by weaker van der Waals inter-actions.

摘要

在标题化合物C₁₈H₁₈O₆中,联苯部分扭转,二面角为29.11 (10)°。由于附近甲氧基的空间位阻,甲氧基羰基与相连环形成的C-C-C-O扭转角分别为-18.3 (3)°和-27.7 (3)°。在没有堆积相互作用且不存在短于2.7 Å的H⋯O接触的情况下,堆积主要由较弱的范德华相互作用主导。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/051f/3998533/aa8ae594ca87/e-70-0o449-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/051f/3998533/aa8ae594ca87/e-70-0o449-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/051f/3998533/aa8ae594ca87/e-70-0o449-fig1.jpg

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