Alexandropoulos Dimitris I, Fournet Adeline, Cunha-Silva Luís, Mowson Andrew M, Bekiari Vlasoula, Christou George, Stamatatos Theocharis C
Department of Chemistry, Brock University , L2S 3A1 St. Catharines, Ontario, Canada.
Inorg Chem. 2014 Jun 2;53(11):5420-2. doi: 10.1021/ic500806n. Epub 2014 May 14.
The initial employment of the fluorescent bridging ligand naphthalene-2,3-diol in 4f-metal coordination chemistry has provided access to a new family of Ln(III)8 clusters with a "Christmas-star" topology, single-molecule magnetism behavior, and ligand-centered emissions.
荧光桥连配体萘-2,3-二醇在4f金属配位化学中的首次应用,使得人们能够获得一类具有“圣诞星”拓扑结构、单分子磁体行为以及以配体为中心发射的新型Ln(III)8簇合物。