Zhong Hai, Wang Guofeng, Song Zhiping, Li Xiang, Tang Hongding, Zhou Yunhong, Zhan Hui
Department of chemistry, Wuhan University, Hubei, 430072, China.
Chem Commun (Camb). 2014 Jun 28;50(51):6768-70. doi: 10.1039/c4cc01572j.
Ferrocene-based polymers, poly(ferrocenyl-methylsilane) and its derivatives, were synthesised by ring-opening polymerization. The product shows promising cathode application in Li-ion, Na-ion and all-organic batteries. The ultra-high power density, excellent cycling stability and decent capacity performance makes it comparable or even superior to the conventional inorganic electrode materials.
基于二茂铁的聚合物,聚(二茂铁基甲基硅烷)及其衍生物,通过开环聚合反应合成。该产物在锂离子电池、钠离子电池和全有机电池中展现出了有前景的阴极应用。超高的功率密度、出色的循环稳定性和良好的容量性能使其与传统无机电极材料相当甚至更具优势。