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光催化 Au-Bi2S3 杂化纳米结构。

Photocatalytic Au-Bi2S3 heteronanostructures.

机构信息

Department of Materials Science and Centre for Advanced Materials, Indian Association for the Cultivation of Science, Kolkata 700032 (India) http://iacs.res.in/matsc/msnp/

出版信息

Angew Chem Int Ed Engl. 2014 Jun 23;53(26):6743-6. doi: 10.1002/anie.201402709. Epub 2014 May 20.

DOI:10.1002/anie.201402709
PMID:24844409
Abstract

Au-Bi2S3 heteronanostructure photocatalysts were designed in which the coupling of a metal plasmon and a semiconductor exciton aids the absorption of solar light, enhances charge separation, and results in improved catalytic activity. Furthermore, these nanostructures show a unique pattern of structural combination, with Au nanoparticles positioned at the center of Bi2S3 nanorods. The chemistry of formation of these nanostructures, their epitaxy at the junction, and their photoconductance were studied, as well as their photoresponse properties.

摘要

Au-Bi2S3 异质纳米结构光催化剂的设计中,金属等离子体和半导体激子的耦合有助于太阳光的吸收,增强电荷分离,从而提高催化活性。此外,这些纳米结构显示出独特的结构组合模式,其中 Au 纳米颗粒位于 Bi2S3 纳米棒的中心。研究了这些纳米结构的形成化学、在界面处的外延以及它们的光电导性,以及它们的光响应特性。

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