Liu Shiwen, Lv Meiyun, Xiao Daoan, Li Xiaogang, Zhou Xiuling, Guo Mengping
Institute of Coordination Catalysis, College of Chemistry and Bio-engineering, Yichun University, Yichun 336000, PR China.
Org Biomol Chem. 2014 Jul 7;12(25):4511-6. doi: 10.1039/c3ob42517g.
Glycine, as a kind of commercially available and inexpensive ligand, is used to prepare an air-stable and water-soluble catalyst for the Suzuki-Miyaura reaction in our study. In the presence of 0.1% [PdCl2(NH2CH2COOH)2] as the catalyst, extremely excellent catalytic activity towards the Suzuki-Miyaura coupling of aryl halides containing the carboxyl group with various aryl boronic acids is observed at room temperature under air in neat water.
在我们的研究中，甘氨酸作为一种市售且廉价的配体，用于制备用于铃木-宫浦反应的空气稳定且水溶性的催化剂。在0.1% [PdCl₂(NH₂CH₂COOH)₂]作为催化剂的情况下，在室温下于空气中的纯水中，观察到其对含羧基的芳基卤化物与各种芳基硼酸的铃木-宫浦偶联反应具有极其优异的催化活性。
