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具有聚集诱导磷光发射(AIPE)的新型离子双核铱(III)席夫碱配合物。

New ionic dinuclear Ir(III) Schiff base complexes with aggregation-induced phosphorescent emission (AIPE).

作者信息

Li Guangfu, Wu Yong, Shan Guogang, Che Weilong, Zhu Dongxia, Song Baiqiao, Yan Likai, Su Zhongmin, Bryce Martin R

机构信息

Institute of Functional Material Chemistry, Faculty of Chemistry, Northeast Normal University, Renmin Road 5268, Changchun, 130024, P.R. China.

出版信息

Chem Commun (Camb). 2014 Jul 7;50(53):6977-80. doi: 10.1039/c4cc01799d. Epub 2014 May 23.

DOI:10.1039/c4cc01799d
PMID:24852610
Abstract

Two new ionic dinuclear Ir(III) Schiff base complexes which are straightforward to synthesise have luminescence quantum yields as high as 37% in neat films. These are the first examples of dinuclear ionic Ir(III) complexes that display aggregation-induced phosphorescent emission (AIPE).

摘要

两种易于合成的新型离子双核铱(III)席夫碱配合物在纯薄膜中的发光量子产率高达37%。这些是显示聚集诱导磷光发射(AIPE)的双核离子铱(III)配合物的首个实例。

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