State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, Jilin 130012 (China).
Angew Chem Int Ed Engl. 2014 Jun 16;53(25):6454-8. doi: 10.1002/anie.201402950. Epub 2014 May 22.
A new approach to preparing 3D microporous conductive polymer has been demonstrated in the electrochemical synthesis of a porous polyaniline network with the utilization of a MOF thin film supported on a conducting substrate. The prepared porous polyaniline with well-defined uniform micropores of 0.84 nm exhibits a high BET surface area of 986 m(2) g(-1) and a high electric conductivity of 0.125 S cm(-1) when doped with I2, which is superior to existing porous conducting materials of porous MOFs, CMPs, and COFs.
一种新的方法被用于制备 3D 微孔导电聚合物，即在导电基底上支撑的 MOF 薄膜的存在下，电化学合成具有多孔聚苯胺网络的多孔聚吡咯。所制备的具有均匀微孔（0.84nm）的多孔聚苯胺的 BET 表面积高达 986m(2)g(-1)，并且在掺杂 I2 时具有 0.125Scm(-1)的高电导率，优于现有的多孔导电材料，如多孔 MOFs、CMPs 和 COFs。
