Taras Shevchenko National University of Kyiv, 64/13, Volodymyrska Street, 01601 Kyiv, Ukraine.
Laboratory of Thermodynamics and Surface Treatment of Materials University Constantine1, B.P. 325 Route Ain El Bey, Constantine 25017, Algeria.
Nanoscale Res Lett. 2014 May 6;9(1):213. doi: 10.1186/1556-276X-9-213. eCollection 2014.
In this work, we studied a nanocomposite material made from fluoroplastic which contains 20 wt.% multi-walled nanotubes. In order to complete the present work, we have used different thermodynamic and mechanical techniques. The introduction of nanotubes in the F4 polymer matrix has completely changed the tribological and thermodynamic properties of the studied nanocomposite material. The compression strength becomes 20% higher than that of the F4 polymer matrix. Meanwhile the wear resistance achieves an order of magnitude 100 times greaterthan that of F4. Moreover, a friction coefficient is about 25% to 30% lower than that of a similar material and especially that of F4 material. Differential scanning calorimetric study showed that the glassy phase transition appears at about 330°C, which confirms that the degradation of the studied nanocomposite occurs at relatively higher temperature. This result confirms the one concerning the change in tribological properties. Dilatometric study revealed that the thermal expansion coefficient has been increased. The observed relative elongation measurement change depends on the direction along which the measurement has been done and confirms, in turn, the anisotropic character of the studied material. These results suggest that the metallic materials could be replaced by nanocomposite compounds which present good physical properties.
在这项工作中,我们研究了一种由氟塑料制成的纳米复合材料,其中含有 20wt.%的多壁纳米管。为了完成目前的工作,我们使用了不同的热力学和力学技术。纳米管在 F4 聚合物基体中的引入完全改变了所研究的纳米复合材料的摩擦学和热力学性能。压缩强度比 F4 聚合物基体提高了 20%。同时,耐磨性比 F4 提高了 100 倍。此外,摩擦系数比类似材料,尤其是 F4 材料低约 25%至 30%。差示扫描量热法研究表明,玻璃化转变出现在约 330°C,这证实了所研究的纳米复合材料在相对较高的温度下发生降解。这一结果证实了摩擦学性能变化的结论。热膨胀系数研究表明,热膨胀系数有所增加。观察到的相对伸长测量变化取决于测量的方向,并反过来证实了所研究材料的各向异性特征。这些结果表明,金属材料可以被具有良好物理性能的纳米复合材料所取代。