Shchegolkov Alexandr V, Shchegolkov Aleksei V, Kaminskii Vladimir V, Iturralde Pablo, Chumak Maxim A
Institute of Power Engineering, Instrumentation and Radioelectronics, Tambov State Technical University, Tambov 392000, Russia.
Center for Project Activities, Advanced Engineering School of Electric Transport, Moscow Polytechnic University, Moscow 107023, Russia.
Polymers (Basel). 2024 Dec 30;17(1):71. doi: 10.3390/polym17010071.
The paper presents a review of CNTs synthesis methods and their application as a functional filler to obtain polymer composites for various technical purposes for strain gauges, electrical heating, anti-static coatings, electrically conductive compounds, etc. Various synthesis methods allow CNTs with different morphology and structural properties to be created, which expands the possibilities of the application of such nanoscale structures. Polymers can provide such effects as 'shape memory' and self-repair of mechanical defects. Different combinations of polymers and dispersed fillers influence the change in electrical and thermal conductivity, as well as the positive temperature coefficient of resistance, which makes it possible to achieve the effect of temperature self-regulation during electrical heating. CNTs make it possible to form PTCR (positive temperature coefficient of resistance) in elastomers at lower concentrations, which makes it possible to preserve mechanical strength and use more efficient modes of heat generation. For strain gauges, CNTs improve sensitivity to mechanical effects and extend the measurement range. The use of thermoplastic elastomers provides the temperature of PTCR operation for electric heating at the level of 200 °C (voltage 240 V), which allows such heaters to operate at a power supply from a household electrical network. CNTs-based strain gauges can provide structural condition monitoring of composite materials.
本文综述了碳纳米管的合成方法及其作为功能填料的应用,以获得用于应变片、电加热、抗静电涂层、导电化合物等各种技术目的的聚合物复合材料。各种合成方法能够制备出具有不同形态和结构特性的碳纳米管,这拓展了此类纳米级结构的应用可能性。聚合物可提供诸如“形状记忆”和机械缺陷自修复等效果。聚合物与分散填料的不同组合会影响电导率和热导率的变化,以及电阻的正温度系数,这使得在电加热过程中实现温度自调节效果成为可能。碳纳米管能够在较低浓度下使弹性体形成正温度系数电阻(PTCR),从而能够保持机械强度并采用更高效的发热模式。对于应变片而言,碳纳米管可提高对机械效应的灵敏度并扩展测量范围。使用热塑性弹性体可使电加热的PTCR工作温度达到200°C(电压240V),这使得此类加热器能够在家庭电网供电下运行。基于碳纳米管的应变片可对复合材料的结构状态进行监测。