Gilmore Kerry, Seeberger Peter H
Department for Biomolecular Systems, Max-Planck Institute for Colloids and Interfaces, Am Mühlenberg 1, 14476, Potsdam, Germany.
Chem Rec. 2014 Jun;14(3):410-8. doi: 10.1002/tcr.201402035. Epub 2014 May 30.
Due to the narrow width of tubing/reactors used, photochemistry performed in micro- and mesoflow systems is significantly more efficient than when performed in batch due to the Beer-Lambert Law. Owing to the constant removal of product and facility of flow chemical scalability, the degree of degradation observed is generally decreased and the productivity of photochemical processes is increased. In this Personal Account, we describe a wide range of photochemical transformations we have examined using both visible and UV light, covering cyclizations, intermolecular couplings, radical polymerizations, as well as singlet oxygen oxygenations.
由于所使用的管道/反应器宽度较窄，根据比尔-朗伯定律，在微流和中流系统中进行的光化学比在间歇式系统中进行的效率要高得多。由于产物的不断去除以及流动化学可扩展性的便利，观察到的降解程度通常会降低，光化学过程的生产率会提高。在这篇个人综述中，我们描述了我们使用可见光和紫外光研究的广泛的光化学转化，包括环化反应、分子间偶联反应、自由基聚合反应以及单线态氧氧化反应。
