Zurcher Danielle M, Adhia Yash J, Romero Julián Díaz, McNeil Anne J
Department of Chemistry and Macromolecular Science and Engineering Program, University of Michigan, 930 North University Avenue, Ann Arbor, Michigan 48109-1055, USA.
Chem Commun (Camb). 2014 Jul 25;50(58):7813-6. doi: 10.1039/c4cc02504k.
The process of selecting and modifying a known gelator scaffold to develop a new nitrite-based sensor is described. Five new azo-sulfonate gelators were discovered and characterized. The most promising scaffold exhibits a stable diazonium intermediate, proceeds in a high yield, and gels nitrite-spiked tap, river, and pond water.
本文描述了选择和修饰已知凝胶剂支架以开发新型亚硝酸盐基传感器的过程。发现并表征了五种新型偶氮磺酸盐凝胶剂。最有前景的支架具有稳定的重氮中间体,产率高,并且能使添加了亚硝酸盐的自来水、河水和池塘水凝胶化。