Chen Mingwei, Wang Yuzhong, Xie Yaoming, Wei Pingrong, Gilliard Robert J, Schwartz Nichole A, Schaefer Henry F, Schleyer Paul von R, Robinson Gregory H
Department of Chemistry and the Center for Computational Chemistry, The University of Georgia, Athens, Georgia 30602-2556 (USA).
Chemistry. 2014 Jul 21;20(30):9208-11. doi: 10.1002/chem.201403095. Epub 2014 Jun 6.
Reaction of N-heterocyclic-carbene (NHC)-stabilized disilicon (1) with CuCl gave a carbene-stabilized disilicon-copper(I) chloride complex (2). The nature of the structure and bonding in 2 has been investigated by crystallographic, spectroscopic, and computational methods. The dynamic complexation behavior of 2 was experimentally explored by variable-temperature NMR analysis.
N-杂环卡宾（NHC）稳定的二硅烷（1）与氯化铜反应生成了卡宾稳定的二硅烷-氯化亚铜（I）配合物（2）。通过晶体学、光谱学和计算方法研究了2的结构和键合性质。通过变温核磁共振分析对2的动态络合行为进行了实验探索。
