Wang Yuzhong, Tope Cynthia A, Xie Yaoming, Wei Pingrong, Urbauer Jeffrey L, Schaefer Henry F, Robinson Gregory H
Department of Chemistry and the Center for Computational Chemistry, The University of Georgia, Athens, GA, 30602-2556, USA.
Angew Chem Int Ed Engl. 2020 Jun 2;59(23):8864-8867. doi: 10.1002/anie.201916395. Epub 2020 Apr 8.
Reaction of carbene-stabilized disilicon (1) with the lithium-based dithiolene radical (2 ) affords the first dianionic silicon tris(dithiolene) complex (3). Notably, the formation of 3 represents the unprecedented utilization of carbene-stabilized disilicon (1) as a silicon-transfer agent. The nature of 3 was probed by multinuclear NMR spectroscopy, single-crystal X-ray diffraction, and DFT computations.
卡宾稳定的二硅烷（1）与基于锂的二硫烯自由基（2）反应，得到首个双阴离子三（二硫烯）硅配合物（3）。值得注意的是，3的形成代表了卡宾稳定的二硅烷（1）作为硅转移剂的前所未有的应用。通过多核核磁共振光谱、单晶X射线衍射和密度泛函理论计算对3的性质进行了探究。
