叠氮化物、呋喃和吡咯单元与通过六氢-狄尔斯-阿尔德（HDDA）反应生成的苯炔的环加成反应。
CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS-ALDER (HDDA) REACTION.
作者信息
Chen Junhua, Baire Beeraiah, Hoye Thomas R
机构信息
Department of Chemistry, University of Minnesota, Minneapolis, MN 55455.
出版信息
Heterocycles. 2014 Jan 1;88(2):1191-1200. doi: 10.3987/COM-13-S(S)83.
Abstract
Benzynes can be generated by the intramolecular thermal cycloisomerization of triynes-the title HDDA reaction. We report here that these can be trapped by cycloaddition reaction with trimethylsilyl azide (1,3-dipolar) or a furan or pyrrole (4+2 Diels-Alder).
摘要
苯炔可通过三炔的分子内热环异构化反应生成——即标题中的HDDA反应。我们在此报告，这些苯炔可通过与叠氮基三甲基硅烷（1,3-偶极体）或呋喃或吡咯（4+2狄尔斯-阿尔德反应）的环加成反应捕获。
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