Knowlton E D, Pine D J, Cipelletti L
Department of Chemical Engineering, University of California Santa Barbara, Santa Barbara, CA 93106, USA.
Soft Matter. 2014 Sep 28;10(36):6931-40. doi: 10.1039/c4sm00531g.
We use a custom shear cell coupled to an optical microscope to investigate at the particle level the yielding transition in concentrated emulsions subjected to an oscillatory shear deformation. By performing experiments lasting thousands of cycles on samples at several volume fractions and for a variety of applied strain amplitudes, we obtain a comprehensive, microscopic picture of the yielding transition. We find that irreversible particle motion sharply increases beyond a volume-fraction dependent critical strain, which is found to be in close agreement with the strain beyond which the stress-strain relation probed in rheology experiments significantly departs from linearity. The shear-induced dynamics are very heterogenous: quiescent particles coexist with two distinct populations of mobile and 'supermobile' particles. Dynamic activity exhibits spatial and temporal correlations, with rearrangements events organized in bursts of motion affecting localized regions of the sample. Analogies with other sheared soft materials and with recent work on the transition to irreversibility in sheared complex fluids are briefly discussed.
我们使用一种与光学显微镜相连的定制剪切池,在颗粒层面研究经受振荡剪切变形的浓乳液中的屈服转变。通过对几个体积分数的样品进行持续数千个循环的实验,并针对各种施加的应变幅度,我们获得了屈服转变的全面微观图像。我们发现,不可逆颗粒运动在超过一个与体积分数相关的临界应变时急剧增加,该临界应变与流变学实验中应力 - 应变关系显著偏离线性时的应变密切一致。剪切诱导的动力学非常不均匀:静态颗粒与两种不同的移动和“超移动”颗粒群体共存。动态活性表现出空间和时间相关性,重排事件以影响样品局部区域的运动爆发形式组织起来。简要讨论了与其他剪切软材料以及近期关于剪切复杂流体中不可逆转变的工作的类比。