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基于二次复有理函数实现的具有最佳纹理光捕获的串联硅太阳能电池的时域模拟

Time domain simulation of tandem silicon solar cells with optimal textured light trapping enabled by the quadratic complex rational function.

作者信息

Chung H, Jung K-Y, Tee X T, Bermel P

出版信息

Opt Express. 2014 May 5;22 Suppl 3:A818-32. doi: 10.1364/OE.22.00A818.

Abstract

Amorphous silicon/crystalline silicon (a-Si/c-Si) micromorph tandem cells, with best confirmed efficiency of 12.3%, have yet to fully approach their theoretical performance limits. In this work, we consider a strategy for improving the light trapping and charge collection of a-Si/c-Si micromorph tandem cells using random texturing with adjustable short-range correlations and long-range periodicity. In order to consider the full-spectrum absorption of a-Si and c-Si, a novel dispersion model known as a quadratic complex rational function (QCRF) is applied to photovoltaic materials (e.g., a-Si, c-Si and silver). It has the advantage of accurately modeling experimental semiconductor dielectric values over the entire relevant solar bandwidth from 300-1000 nm in a single simulation. This wide-band dispersion model is then used to model a silicon tandem cell stack (ITO/a-Si:H/c-Si:H/silver), as two parameters are varied: maximum texturing height h and correlation parameter f. Even without any other light trapping methods, our front texturing method demonstrates 12.37% stabilized cell efficiency and 12.79 mA/cm² in a 2 μm-thick active layer.

摘要

非晶硅/晶体硅(a-Si/c-Si)微晶串联电池的最佳确认效率为12.3%,尚未完全达到其理论性能极限。在这项工作中,我们考虑了一种策略,即使用具有可调节短程相关性和长程周期性的随机纹理来改善a-Si/c-Si微晶串联电池的光捕获和电荷收集。为了考虑a-Si和c-Si的全光谱吸收,一种称为二次复有理函数(QCRF)的新型色散模型被应用于光伏材料(例如a-Si、c-Si和银)。它具有在单次模拟中对300-1000nm整个相关太阳带宽内的实验半导体介电值进行精确建模的优点。然后,这个宽带色散模型被用于对硅串联电池堆栈(ITO/a-Si:H/c-Si:H/银)进行建模,其中两个参数发生变化:最大纹理高度h和相关参数f。即使没有任何其他光捕获方法,我们的前表面纹理方法在2μm厚的有源层中也展示出12.37%的稳定电池效率和12.79mA/cm²的电流密度。

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