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共掺杂氧化钛和氧化镁的硼酸锂钾玻璃的热释光剂量学特性及动力学参数

Thermoluminescence dosimetry properties and kinetic parameters of lithium potassium borate glass co-doped with titanium and magnesium oxides.

作者信息

Hashim S, Alajerami Y S M, Ramli A T, Ghoshal S K, Saleh M A, Abdul Kadir A B, Saripan M I, Alzimami K, Bradley D A, Mhareb M H A

机构信息

Department of Physics, Universiti Teknologi Malaysia, 81310 Skudai, Johor, Malaysia.

Department of Physics, Universiti Teknologi Malaysia, 81310 Skudai, Johor, Malaysia; Department of Medical Radiography, Al-Azhar University, Gaza Strip, Palestine.

出版信息

Appl Radiat Isot. 2014 Sep;91:126-30. doi: 10.1016/j.apradiso.2014.05.023. Epub 2014 Jun 2.

Abstract

Lithium potassium borate (LKB) glasses co-doped with TiO2 and MgO were prepared using the melt quenching technique. The glasses were cut into transparent chips and exposed to gamma rays of (60)Co to study their thermoluminescence (TL) properties. The TL glow curve of the Ti-doped material featured a single prominent peak at 230 °C. Additional incorporation of MgO as a co-activator enhanced the TL intensity threefold. LKB:Ti,Mg is a low-Z material (Z(eff)=8.89) with slow signal fading. Its radiation sensitivity is 12 times lower that the sensitivity of TLD-100. The dose response is linear at doses up to 10(3) Gy. The trap parameters, such as the kinetics order, activation energy, and frequency factor, which are related to the glow peak, were determined using TolAnal software.

摘要

采用熔体淬火技术制备了共掺杂TiO₂和MgO的硼酸锂钾(LKB)玻璃。将玻璃切割成透明芯片并暴露于⁶⁰Co的伽马射线中,以研究其热释光(TL)特性。掺钛材料的TL发光曲线在230°C处有一个突出的单峰。额外加入MgO作为共激活剂使TL强度提高了三倍。LKB:Ti,Mg是一种低Z材料(Z(eff)=8.89),信号衰减缓慢。其辐射灵敏度比TLD-100的灵敏度低12倍。在剂量高达10³ Gy时,剂量响应呈线性。使用TolAnal软件确定了与发光峰相关的陷阱参数,如动力学级数、激活能和频率因子。

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