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共掺杂CuO和MgO的Li2CO3-K2CO3-H3BO3玻璃体系的热发光特性

Thermoluminescence properties of Li2CO3-K2CO3-H3BO3glass system co-doped with CuO and MgO.

作者信息

Alajerami Yasser Saleh Mustafa, Hashim Suhairul, Ramli Ahmad Termizi, Saleh Muneer Aziz, Kadni Taiman

机构信息

Department of Physics, Universiti Teknologi Malaysia, Skudai, Johor 81310, Malaysia.

出版信息

Radiat Prot Dosimetry. 2013 Jun;155(1):1-10. doi: 10.1093/rpd/ncs310. Epub 2012 Nov 28.

Abstract

The thermoluminescent properties of boric glass modified with lithium and potassium carbonates (LKB) and co-doped with CuO and MgO are reported for the first time. Two techniques are applied to investigate the effect of dopants and co-dopants on the thermal stimulation properties of LKB. The induced TL glow curves of a CuO-doped sample are found to be at 220°C with a single peak. An enhancement of about three times is shown with the increment of 0.1 mol % MgO as a co-dopant impurity. This enhancement may contribute to the ability of magnesium to create extra electron traps and consequently the energy transfer to monovalent Cu(+) ions. LKB:Cu,Mg is low Z material (Zeff=8.55), and observed 15 times less sensitive than LiF: Mg, Ti (TLD-100). The proposed dosemeter showed good linearity in TL dose-response, low fading and excellent reproducibility with a simple glow curve, and thus, can be used in the radiation dosimetry.

摘要

首次报道了用碳酸锂和碳酸钾改性(LKB)并共掺杂CuO和MgO的硼玻璃的热释光特性。应用两种技术研究掺杂剂和共掺杂剂对LKB热刺激特性的影响。发现掺杂CuO的样品的诱导热释光发光曲线在220°C处有一个单峰。作为共掺杂杂质,随着0.1 mol% MgO的增加,热释光增强约三倍。这种增强可能有助于镁产生额外的电子陷阱,从而实现向一价Cu(+)离子的能量转移。LKB:Cu,Mg是低Z材料(有效原子序数Zeff = 8.55),其灵敏度比LiF:Mg,Ti(TLD-100)低15倍。所提出的剂量计在热释光剂量响应中表现出良好的线性、低衰退以及具有简单发光曲线的优异再现性,因此可用于辐射剂量测定。

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