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2-甲氧基-4-(2-甲氧基苯基)-5,6,7,8,9,10-六氢环辛并[b]吡啶-3-甲腈

2-Meth-oxy-4-(2-meth-oxy-phen-yl)-5,6,7,8,9,10-hexa-hydro-cyclo-octa-[b]pyridine-3-carbo-nitrile.

作者信息

Vishnupriya R, Suresh J, Maharani S, Kumar R Ranjith, Lakshman P L Nilantha

机构信息

Department of Physics, The Madura College, Madurai 625 011, India.

Department of Organic Chemistry, School of Chemistry, Madurai Kamaraj University, Madurai 625 021, India.

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2014 May 10;70(Pt 6):o656. doi: 10.1107/S1600536814010332. eCollection 2014 Jun 1.

DOI:10.1107/S1600536814010332
PMID:24940240
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC4051075/
Abstract

In the title compound, C20H22N2O2, the central pyridine ring forms a dihedral angle of 76.32 (8)° with the pseudo-axial benzene ring. The cyclo-octane ring adopts a twisted boat chair conformation. In the crystal, weak inter-molecular C-H⋯π inter-actions between inversion-related mol-ecules result in the formation of linear double chains along the b-axis direction.

摘要

在标题化合物C₂₀H₂₂N₂O₂中,中心吡啶环与假轴向苯环形成76.32 (8)°的二面角。环辛烷环呈扭船式构象。在晶体中,与反演相关分子之间的弱分子间C-H⋯π相互作用导致沿b轴方向形成线性双链。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf80/4051075/b0b3a19c2b14/e-70-0o656-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf80/4051075/828e40781578/e-70-0o656-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf80/4051075/b0b3a19c2b14/e-70-0o656-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf80/4051075/828e40781578/e-70-0o656-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cf80/4051075/b0b3a19c2b14/e-70-0o656-fig2.jpg

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