（3Z）-3- [（Z）-2-（2-氧代吲哚啉-3-基亚基）肼-1-基亚基]吲哚啉-2-酮0.17水合物
(3Z)-3-[(Z)-2-(2-Oxoindolin-3-yl-idene)hydrazin-1-yl-idene]indolin-2-one 0.17-hydrate.
作者信息
Liu Yong-Hong, Zhao Lei, Liu Ming-Xuan, Lin Hai, Li Jing-Jing
机构信息
College of Chemistry and Chemical Engineering, Yangzhou University, Jiangsu Provincial Key Laboratory of Environmental Material & Engineering, Yangzhou, 225002, People's Republic of China.
College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, People's Republic of China.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 May 31;70(Pt 6):o721. doi: 10.1107/S1600536814011805. eCollection 2014 Jun 1.
In the title compound, C16H10N4O2·0.17H2O, prepared by the one-step condensation reaction of isatin with hydrazine hydrate under microwave irradiation, the complete organic mol-ecule is generated by crystallographic inversion symmetry and therefore exists in an S-trans conformation. In the crystal, mol-ecules are linked by N-H⋯O hydrogen bonds, generating a three-dimensional framework with [001] channels, which are occupied by the disordered water mol-ecules.
在标题化合物C₁₆H₁₀N₄O₂·0.17H₂O中，通过异吲哚酮与水合肼在微波辐射下的一步缩合反应制备，完整的有机分子由晶体学反演对称性产生，因此以S-反式构象存在。在晶体中，分子通过N-H⋯O氢键相连，形成具有[001]通道的三维框架，这些通道被无序的水分子占据。
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