Adonin Sergey A, Peresypkina Eugenia V, Sokolov Maxim N, Korolkov Ilya V, Fedin Vladimir P
Nikolaev Institute of Inorganic Chemistry SB RAS , 630090, Lavrentiev prosp. 3, Novosibirsk, Russia.
Inorg Chem. 2014 Jul 7;53(13):6886-92. doi: 10.1021/ic500710t. Epub 2014 Jun 19.
Octamolybdate complexes TBA4[Mo8O26(BiX3)2] (TBA = n-tetrabutylammonium, X = Cl (1), Br (2), I (3)) were obtained by straightforward syntheses from TBA4[Mo8O26] and corresponding Bi(III) halides in MeCN. All compounds were structurally characterized; in all cases, {BiX3} fragments are coordinated by two oxygen atoms of polyoxometalate core. Occurring polymorphism is also discussed.
通过在乙腈中由四丁基铵钼酸盐（TBA4[Mo8O26]）和相应的铋（III）卤化物直接合成得到了八钼酸盐配合物TBA4[Mo8O26(BiX3)2]（TBA = 正四丁基铵，X = Cl（1），Br（2），I（3））。对所有化合物进行了结构表征；在所有情况下，{BiX3}片段由多金属氧酸盐核的两个氧原子配位。还讨论了出现的多晶型现象。
