Daffé M
Centre de Recherche de Biochimie et Génétique Cellulaires du CNRS, Université Paul Sabatier, Toulouse, France.
Biochim Biophys Acta. 1989 Apr 3;1002(2):257-60. doi: 10.1016/0005-2760(89)90295-6.
Mono- and two-dimensional 1H-NMR allowed the structural elucidation of a glycolipid belonging to the phenolic mycosides series: 2,3,4-tri-0-methyl fucopyranosyl (alpha 1----3) rhamnopyranosyl (alpha 1----3) rhamnopyranosyl (alpha 1----dimycocerosyl) phenol phthiocerol. It shares with the major phenolic glycolipid the two terminal sugar residues, suggesting its potential antigenicity. The glycolipid may also represent an intermediate in the biosynthesis of the major one.
一维和二维¹H-NMR技术实现了对一种属于酚型霉菌糖苷系列糖脂的结构解析：2,3,4-三-O-甲基呋喃岩藻糖基(α1→3)鼠李糖基(α1→3)鼠李糖基(α1→二霉菌酸基)苯酚结核硬脂醇。它与主要的酚型糖脂共有两个末端糖残基，提示其潜在的抗原性。该糖脂也可能是主要糖脂生物合成过程中的一个中间体。
