具有冠状Co(7)自旋簇次级构筑单元的双层三角晶格呈现出高自旋阻挫。
A bilayer triangular lattice with crown-like Co(7) spin cluster SBUs exhibiting high spin frustration.
作者信息
Li Ya-Min, Lun Hui-Jie, Xiao Chang-Yu, Xu Yan-Qing, Wu Ling, Yang Jing-He, Niu Jing-Yang, Xiang Sheng-Chang
机构信息
Henan Key Laboratory of Polyoxometalate, Institute of Molecular and Crystal Engineering, College of Chemistry and Chemical Engineering, Henan University, Kaifeng, Henan 475004, China.
出版信息
Chem Commun (Camb). 2014 Aug 11;50(62):8558-60. doi: 10.1039/c4cc02910k.
PMID:24955442
Abstract
A novel bilayer metal-organic framework is assembled with a perfect intralayer triangular subnet and ideal interlayer Td arrangement between unprecedented crown-like Co7 cluster units, exhibiting high spin frustration.
摘要
一种新型双层金属有机框架由完美的层内三角形子网和前所未有的冠状Co7簇单元之间理想的层间Td排列组装而成，表现出高自旋阻挫。
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