Department of Mechanical & Industrial Engineering, University of Toronto, 5 King's College Road, Toronto M5S 3G8, Ontario (Canada).
Angew Chem Int Ed Engl. 2014 Jul 28;53(31):7992-8002. doi: 10.1002/anie.201403719. Epub 2014 Jun 24.
Carbon dioxide (CO2) sequestration, storage and recycling will greatly benefit from comprehensive studies of physical and chemical gas-liquid processes involving CO2. Over the past five years, microfluidics emerged as a valuable tool in CO2-related research, due to superior mass and heat transfer, reduced axial dispersion, well-defined gas-liquid interfacial areas and the ability to vary reagent concentrations in a high-throughput manner. This Minireview highlights recent progress in microfluidic studies of CO2-related processes, including dissolution of CO2 in physical solvents, CO2 reactions, the utilization of CO2 in materials science, and the use of supercritical CO2 as a "green" solvent.
二氧化碳(CO2)的捕集、封存和再循环将极大地受益于对涉及 CO2 的物理和化学气液过程的综合研究。在过去的五年中,由于具有优越的传质和传热性能、较低的轴向扩散、明确的气液界面以及能够高通量地改变试剂浓度,微流控技术成为 CO2 相关研究的一种有价值的工具。本文综述了近年来在 CO2 相关过程的微流控研究方面的进展,包括物理溶剂中 CO2 的溶解、CO2 反应、CO2 在材料科学中的利用以及超临界 CO2 作为“绿色”溶剂的应用。