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玉米秸秆在快速热解过程中炭化,作为流化床反应器中制备活性炭的前驱体材料。

Corn stalks char from fast pyrolysis as precursor material for preparation of activated carbon in fluidized bed reactor.

机构信息

Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, China.

Key Laboratory of Biofuels, Qingdao Institute of Bioenergy and Bioprocess Technology, Chinese Academy of Sciences, Qingdao, China.

出版信息

Bioresour Technol. 2014 Sep;167:551-4. doi: 10.1016/j.biortech.2014.05.123. Epub 2014 Jun 9.

Abstract

Corn stalks char from fast pyrolysis was activated by physical and chemical activation process in a fluidized bed reactor. The structure and morphology of the carbons were characterized by N2 adsorption and SEM. Effects of activation time and activation agents on the structure of activation carbon were investigated. The physically activated carbons with CO2 have BET specific surface area up to 880 m(2)/g, and exhibit microporous structure. The chemically activated carbons with H3PO4 have BET specific surface area up to 600 m(2)/g, and exhibit mesoporous structure. The surface morphology shows that physically activated carbons exhibit fibrous like structure in nature with long ridges, resembling parallel lines. Whereas chemically activated carbons have cross-interconnected smooth open pores without the fibrous like structure.

摘要

玉米秸秆在流化床反应器中通过物理和化学活化过程进行快速热解炭化。通过氮气吸附和 SEM 对炭的结构和形态进行了表征。考察了活化时间和活化剂对活性炭结构的影响。用 CO2 进行物理活化得到的活性炭的 BET 比表面积高达 880 m(2)/g,呈微孔结构。用 H3PO4 进行化学活化得到的活性炭的 BET 比表面积高达 600 m(2)/g,呈介孔结构。表面形态表明,物理活化的活性炭具有天然的纤维状结构,长有脊,类似于平行线。而化学活化的活性炭则具有互穿的光滑开放孔,没有纤维状结构。

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