Department of Chemistry, Faculty of Science, University of Ibadan, Ibadan, Nigeria.
Basel Convention Coordinating Centre for Training and Technology Transfer for the African Region, University of Ibadan, 1 Ijoma Road, Ibadan, Nigeria.
Environ Sci Pollut Res Int. 2015 Oct;22(19):14502-14. doi: 10.1007/s11356-014-3228-6. Epub 2014 Jul 3.
This study investigated the material/substance flow of polybrominated diphenyl ethers listed in the Stockholm Convention (SC) as persistent organic pollutant (POP-PBDEs) in the most relevant plastic fractions in Nigeria. Considering the prohibition of production and the use of POP-PBDEs and knowing that these pollutants are still contained in electrical and electronic equipment (EEE) and associated wastes (WEEE), it is necessary to determine their flows, especially in developing countries with limited end-of-life management. Following the inventory approach of the SC Guidance and utilizing the existing national e-waste inventory together with monitoring data, a material/substance flow analysis was conducted using the STAN tool. Within the period of 2000 to 2010, the total import for EEE/WEEE in Category 3 and 4 was approximately 8 million tonnes (Mt) containing approximately 2.4 Mt of polymers. For the inventory year 2010, it was estimated that from these polymers, about 0.8 Mt was still in stock and 1.6 Mt has reached the end-of-life. It was also estimated that approximately 1.1 Mt has ended in dumpsites, 0.3 Mt was burned in the open, and 0.2 Mt was recycled. In the plastic fractions, 1,270 t of POP-PBDEs was contained with about 370 t still in use/stock and approximately 900 t has entered the end-of-life phase. All three major end-of-life treatments result in environmental pollution with associated exposure risk. The implementation of the Stockholm Convention represents an important opportunity to improve this management situation in Nigeria and other developing countries.
本研究调查了斯德哥尔摩公约(SC)中列为持久性有机污染物(POP-PBDEs)的多溴二苯醚(PBDEs)在尼日利亚最相关塑料部分的物质/物质流。考虑到 POP-PBDEs 的生产和使用已被禁止,并且这些污染物仍包含在电气和电子设备(EEE)及相关废物(WEEE)中,因此有必要确定它们的流动情况,尤其是在有限的废物末端管理的发展中国家。本研究采用 SC 指南的清单方法,利用现有的国家电子废物清单和监测数据,使用 STAN 工具进行物质/物质流分析。在 2000 年至 2010 年期间,第 3 类和第 4 类 EEE/WEEE 的总进口量约为 800 万吨(Mt),其中约含有 240 万吨聚合物。对于 2010 年的清单年,据估计,这些聚合物中约有 0.8 Mt 仍在库存中,1.6 Mt 已达到使用寿命终点。据估计,约有 1.1 Mt 最终进入了垃圾填埋场,0.3 Mt 在露天焚烧,0.2 Mt 被回收利用。在塑料部分,含有 1,270 吨的 POP-PBDEs,其中约有 370 吨仍在使用/库存中,约有 900 吨已进入使用寿命终点阶段。所有这三种主要的废物末端处理方式都会导致环境污染和相关的暴露风险。《斯德哥尔摩公约》的实施为改善尼日利亚和其他发展中国家的废物管理状况提供了一个重要机会。