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凝胶中自穿环聚合物的动力学

Dynamics of self-threading ring polymers in a gel.

作者信息

Michieletto Davide, Marenduzzo Davide, Orlandini Enzo, Alexander Gareth P, Turner Matthew S

机构信息

Department of Physics and Centre for Complexity Science, University of Warwick, Coventry CV4 7AL, UK.

出版信息

Soft Matter. 2014 Aug 28;10(32):5936-44. doi: 10.1039/c4sm00619d.

Abstract

We study the dynamics of ring polymers confined to diffuse in a background gel at low concentrations. We do this in order to probe the inter-play between topology and dynamics in ring polymers. We develop an algorithm that takes into account the possibility that the rings hinder their own motion by passing through themselves, i.e. "self-threading". Our results suggest that the number of self-threadings scales extensively with the length of the rings and that this is substantially independent of the details of the model. The slowing down of the rings' dynamics is found to be related to the fraction of segments that can contribute to the motion. Our results give a novel perspective on the motion of ring polymers in a gel, for which a complete theory is still lacking, and may help us to understand the irreversible trapping of ring polymers in gel electrophoresis experiments.

摘要

我们研究了在低浓度背景凝胶中扩散的环形聚合物的动力学。我们这样做是为了探究环形聚合物中拓扑结构与动力学之间的相互作用。我们开发了一种算法,该算法考虑到环通过自身穿过(即“自穿线”)而阻碍自身运动的可能性。我们的结果表明,自穿线的数量与环的长度成比例地大量增加,并且这基本上与模型的细节无关。发现环动力学的减慢与可参与运动的链段分数有关。我们的结果为凝胶中环聚合物的运动提供了一个全新的视角,目前仍缺乏关于此的完整理论,并且可能有助于我们理解凝胶电泳实验中环聚合物的不可逆捕获。

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