Wu Jie, Sun Shu, Feng Xiaoqing, Shi Jianbing, Hu Xiao-Yu, Wang Leyong
Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.
Chem Commun (Camb). 2014 Aug 21;50(65):9122-5. doi: 10.1039/c4cc03127j.
A novel TPE-functionalized pillar[5]arene (TPEP5) was successfully synthesized, and the motion of the TPE motif was restricted via pillararene-based host–guest recognition-mediated cross-linking, resulting in the efficient “turn-on” of fluorescence emission based on the AIE mechanism.
成功合成了一种新型的TPE功能化柱[5]芳烃(TPEP5),通过基于柱芳烃的主客体识别介导的交联作用限制了TPE基序的运动,从而基于聚集诱导发光(AIE)机制实现了荧光发射的有效“开启”。