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基于四苯基乙烯功能化柱[5]芳烃通过主客体识别的可控聚集诱导发光。

Controllable aggregation-induced emission based on a tetraphenylethylene-functionalized pillar[5]arene via host-guest recognition.

作者信息

Wu Jie, Sun Shu, Feng Xiaoqing, Shi Jianbing, Hu Xiao-Yu, Wang Leyong

机构信息

Key Laboratory of Mesoscopic Chemistry of MOE, Center for Multimolecular Organic Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, China.

出版信息

Chem Commun (Camb). 2014 Aug 21;50(65):9122-5. doi: 10.1039/c4cc03127j.

DOI:10.1039/c4cc03127j
PMID:24985745
Abstract

A novel TPE-functionalized pillar[5]arene (TPEP5) was successfully synthesized, and the motion of the TPE motif was restricted via pillararene-based host–guest recognition-mediated cross-linking, resulting in the efficient “turn-on” of fluorescence emission based on the AIE mechanism.

摘要

成功合成了一种新型的TPE功能化柱[5]芳烃(TPEP5),通过基于柱芳烃的主客体识别介导的交联作用限制了TPE基序的运动,从而基于聚集诱导发光(AIE)机制实现了荧光发射的有效“开启”。

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