六水合双(过氧邻苯二甲酸)镁作为温和高效的氧化剂用于硒酮的合成。
Magnesium bis(monoperoxyphthalate) hexahydrate as mild and efficient oxidant for the synthesis of selenones.
机构信息
Dipartimento di Scienze Farmaceutiche, Università di Perugia, via del Liceo 1, 06123 Perugia, Italy.
Dipartimento di Chimica, Biologia e Biotecnologia, Università di Perugia, via Elce di Sotto 8, 06123 Perugia, Italy.
出版信息
Beilstein J Org Chem. 2014 Jun 2;10:1267-71. doi: 10.3762/bjoc.10.127. eCollection 2014.
A new, efficient and mild method for the direct oxidation of selenides to selenones using magnesium bis(monoperoxyphthalate) hexahydrate (MMPP) has been developed. Noteworthy this transformation proceeds at room temperature, employs a cheap and safety oxidant and has a broad functional group tolerance. Moreover, the produced selenones could be useful intermediates for the synthesis of different heterocyclic compounds.
现已开发出一种使用双(过氧邻苯二甲酸)镁六水合物（MMPP）将硒化物直接氧化为硒酮的新型、高效且温和的方法。值得注意的是，此转化在室温下进行，使用廉价且安全的氧化剂，具有广泛的官能团耐受性。此外，生成的硒酮可能是合成不同杂环化合物的有用中间体。
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