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现代有机硒试剂合成策略:聚焦乙烯硒酮。

Modern Synthetic Strategies with Organoselenium Reagents: A Focus on Vinyl Selenones.

机构信息

Group of Catalysis, Synthesis and Organic Green Chemistry, Department of Pharmaceutical Sciences, University of Perugia, Via del Liceo, 06123 Perugia, Italy.

出版信息

Molecules. 2021 May 25;26(11):3148. doi: 10.3390/molecules26113148.

DOI:10.3390/molecules26113148
PMID:34070372
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC8197542/
Abstract

In recent years, vinyl selenones were rediscovered as useful building blocks for new synthetic transformations. This review will highlight these advances in the field of multiple-bond-forming reactions, one-pot synthesis of carbo- and heterocycles, enantioselective construction of densely functionalized molecules, and total synthesis of natural products.

摘要

近年来,乙烯硒酮作为新型合成转化的有用构建块被重新发现。本综述将重点介绍这些在多键形成反应、一锅法合成碳环和杂环、手性密集官能化分子的构建以及天然产物的全合成领域的进展。

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