Lieb Elliott H, Yngvason Jakob
Departments of Mathematics and Physics , Princeton University , Princeton, NJ 08544, USA.
Faculty of Physics, University of Vienna, Vienna, Austria ; Erwin Schrödinger Institute for Mathematical Physics, Vienna, Austria.
Proc Math Phys Eng Sci. 2014 Jul 8;470(2167):20140192. doi: 10.1098/rspa.2014.0192.
In our derivation of the second law of thermodynamics from the relation of adiabatic accessibility of equilibrium states, we stressed the importance of being able to scale a system's size without changing its intrinsic properties. This leaves open the question of defining the entropy of macroscopic, but unscalable systems, such as gravitating bodies or systems where surface effects are important. We show here how the problem can be overcome, in principle, with the aid of an 'entropy meter'. An entropy meter can also be used to determine entropy functions for non-equilibrium states and mesoscopic systems.
在我们从平衡态的绝热可及性关系推导热力学第二定律的过程中,我们强调了能够在不改变系统固有性质的情况下缩放其大小的重要性。这就留下了一个问题,即如何定义宏观但不可缩放系统的熵,例如引力体或表面效应很重要的系统。我们在此展示了原则上如何借助“熵计”来克服这个问题。熵计还可用于确定非平衡态和介观系统的熵函数。