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[复合污染干旱黄土中秸秆腐解的光谱特征]

[Spectral characteristics of decomposition of incorporated straw in compound polluted arid loess].

作者信息

Fan Chun-Hui, Zhang Ying-Chao, Xu Ji-Ting, Wang Jia-Hong

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2014 Apr;34(4):1045-9.

Abstract

The original loess from western China was used as soil sample, the spectral methods of scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDS), elemental analysis, Fourier transform infrared spectroscopy (FT-IR) and 13C nuclear magnetic resonance (13C NMR) were used to investigate the characteristics of decomposed straw and formed humic acids in compound polluted arid loess. The SEM micrographs show the variation from dense to decomposed surface, and finally to damaged structure, and the EDS data reveal the phenomenon of element transfer. The newly-formed humic acids are of low aromaticity, helpful for increasing the activity of organic matters in loess. The FTIR spectra in the whole process are similar, indicating the complexity of transformation dynamics of humic acids. The molecular structure of humic acids becomes simpler, shown from 13C NMR spectra. The spectral methods are useful for humic acids identification in loess region in straw incorporation process.

摘要

以中国西部原生黄土为土样,采用扫描电子显微镜-能量色散X射线光谱法(SEM-EDS)、元素分析、傅里叶变换红外光谱法(FT-IR)和13C核磁共振波谱法(13C NMR)研究了复合污染干旱黄土中秸秆分解及腐殖酸形成的特征。扫描电子显微镜图像显示了从致密表面到分解表面,最终到结构破坏的变化,能量色散X射线光谱数据揭示了元素转移现象。新形成的腐殖酸芳香性较低,有助于提高黄土中有机物的活性。整个过程中的傅里叶变换红外光谱相似,表明腐殖酸转化动力学的复杂性。从13C核磁共振波谱可以看出,腐殖酸的分子结构变得更简单。光谱方法有助于识别秸秆掺入过程中黄土区域的腐殖酸。

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