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用于测定颗粒磁化率的零速度磁泳法

Zero-velocity magnetophoretic method for the determination of particle magnetic susceptibility.

作者信息

Watarai Hitoshi, Duc Hoang Trong Tien, Lan Tran Thi Ngoc, Zhang Tianyi, Tsukahara Satoshi

机构信息

Institute for NanoScience Design, Osaka University.

出版信息

Anal Sci. 2014;30(7):745-9. doi: 10.2116/analsci.30.745.

Abstract

A simple zero-velocity method to determine the particle magnetic susceptibility by measuring the magnetophoretic velocity was proposed. The principle is that the magnetophoretic velocity of a particle in a liquid medium must be zero when the magnetic susceptibilities of the medium and the particle are equal, or the gravity force and the magnetophoretic force are balanced. By changing the medium magnetic susceptibility and measuring the magnetophoretic velocity of a particle, the particle magnetic susceptibility was determined from the medium magnetic susceptibility under the zero-velocity condition. The feasibility of the method was demonstrated for polystyrene particles using a Dy(III) solution in the horizontal migration mode and different organic solvents in the vertical migration mode.

摘要

提出了一种通过测量磁泳速度来确定颗粒磁化率的简单零速度方法。其原理是,当介质和颗粒的磁化率相等,或者重力和磁泳力平衡时,颗粒在液体介质中的磁泳速度必须为零。通过改变介质磁化率并测量颗粒的磁泳速度,在零速度条件下根据介质磁化率确定颗粒磁化率。使用Dy(III)溶液在水平迁移模式下以及不同有机溶剂在垂直迁移模式下对聚苯乙烯颗粒证明了该方法的可行性。

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