Chlorine-35 solid-state NMR spectroscopy as an indirect probe of germanium oxidation state and coordination environment in germanium chlorides.
作者信息
Hanson Margaret A, Terskikh Victor V, Baines Kim M, Huang Yining
机构信息
Department of Chemistry, The University of Western Ontario , London, Ontario, Canada N6A 5B7.
出版信息
Inorg Chem. 2014 Jul 21;53(14):7377-88. doi: 10.1021/ic500728w. Epub 2014 Jun 20.
PMID:25041238
Abstract
Due to the prevalence of Ge-Cl bonds in germanium chemistry and the inherent challenges of germanium-73 NMR spectroscopy, chlorine-35 NMR spectroscopy was investigated as an indirect method of characterization for these ubiquitous and useful compounds. Chlorine-35 NMR parameters were correlated with structural metrics as well as the oxidation state of germanium.
摘要
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