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基于 Pd 纳米粒子表面调制的 LaAlO3/SrTiO3 异质结构的高灵敏度气体传感器。

Highly sensitive gas sensor by the LaAlO3 /SrTiO3 heterostructure with Pd nanoparticle surface modulation.

机构信息

Department of Applied Physics, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, P. R. China.

出版信息

Adv Mater. 2014 Sep 10;26(34):5962-8. doi: 10.1002/adma.201401597. Epub 2014 Jul 10.

DOI:10.1002/adma.201401597
PMID:25042007
Abstract

The palladium nanoparticle (Pd NP)-decorated LaAlO3 /SrTiO3 (LAO/STO) heterostructure is for the first time used as a hydrogen-gas sensor with very high sensitivity and workability at room temperature. The outstanding gas-sensing properties are due to the Pd NPs' catalytic effect to different gases, resulting in charge coupling between the gas molecules and the two-dimensional electron gas (2DEG) through the Pd NPs by either a direct charge exchange or a change of the electron affinity. These results provide insight into the emerging properties at LAO/STO interfaces.

摘要

钯纳米粒子(Pd NP)修饰的 LaAlO3/SrTiO3(LAO/STO)异质结构首次被用作室温下具有高灵敏度和可操作性的氢气传感器。优异的气体传感性能归因于 Pd NPs 对不同气体的催化作用,通过 Pd NPs 直接电荷交换或电子亲和性的变化,导致气体分子与二维电子气(2DEG)之间的电荷耦合。这些结果深入了解了 LAO/STO 界面的新兴特性。

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