铜催化的芳基烯烃分子间叠氮氰化反应
Copper-catalyzed intermolecular azidocyanation of aryl alkenes.
作者信息
Xu Li, Mou Xue-Qing, Chen Zhi-Min, Wang Shao-Hua
机构信息
School of Pharmacy, Lanzhou University, Lanzhou 730000, P. R. China.
出版信息
Chem Commun (Camb). 2014 Sep 21;50(73):10676-9. doi: 10.1039/c4cc04640d. Epub 2014 Jul 31.
PMID:25079085
Abstract
A copper-catalyzed Markovnikov-type intermolecular azidocyanation of aryl alkenes has been developed to give a series of α-azido-propanenitriles in moderate to good yields. This method may provide a potential strategy for the synthesis of corresponding 3-amino-2-arylpropanoic acid.
摘要
已开发出一种铜催化的芳基烯烃的马氏规则型分子间叠氮氰化反应，以中等至良好的产率得到一系列α-叠氮基丙腈。该方法可能为相应的3-氨基-2-芳基丙酸的合成提供一种潜在策略。
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