铜催化的烯丙基间三氟甲基叠氮化物和三氟甲基硫氰化物反应：CF3 含烯丙基叠氮化物和硫氰酸盐的有效合成方法。
Copper-Catalyzed Intermolecular Trifluoromethylazidation and Trifluoromethylthiocyanation of Allenes: Efficient Access to CF3-Containing Allyl Azides and Thiocyanates.
机构信息
†Engineering Research Centre of Pharmaceutical Process Chemistry, Ministry of Education, School of Pharmacy, East China University of Science and Technology, 130 Meilong Road, Shanghai, China 200237.
‡State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Lingling Road, Shanghai, China 200032.
出版信息
Org Lett. 2015 Jul 17;17(14):3580-3. doi: 10.1021/acs.orglett.5b01677. Epub 2015 Jul 9.
A mild and efficient method for copper-catalyzed trifluoromethylazidation and trifluoromethylthiocyanation of allenes was explored. A series of CF3-containing allyl azides and thiocyanates were obtained with high yields and good stereoselectivities, which can be used for further transformation to some valuable compounds.
探索了一种温和高效的铜催化丙二烯三氟甲基叠氮化和三氟甲基硫氰化的方法。一系列含 CF3 的烯丙基叠氮化物和硫氰酸酯以高产率和良好的立体选择性得到，它们可用于进一步转化为一些有价值的化合物。
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