Liu Jia, Ruffieux Pascal, Feng Xinliang, Müllen Klaus, Fasel Roman
Empa, Swiss Federal Laboratories for Materials Science and Technology, Ueberlandstrasse 129, 8600 Duebendorf, Switzerland.
Chem Commun (Camb). 2014 Oct 4;50(76):11200-3. doi: 10.1039/c4cc02859g.
Surface-assisted cyclotrimerization of arylalkynes was studied on Au(111) by means of scanning tunneling microscopy (STM) under ultra-high vacuum (UHV) conditions. Upon thermal activation, cyclotrimerization of 1,3,5-tris-(4-ethynylphenyl)benzene proceeds readily and with high selectivity, and results in two-dimensional covalently bonded polyphenylene nanostructures exhibiting a honeycomb topology.
在超高真空（UHV）条件下，利用扫描隧道显微镜（STM）对芳基炔烃在Au(111)上的表面辅助环三聚反应进行了研究。在热活化作用下，1,3,5-三（4-乙炔基苯基）苯的环三聚反应容易且具有高选择性地进行，并生成呈现蜂窝拓扑结构的二维共价键合聚苯撑纳米结构。
