腈的界面氢化和脱氨以选择性合成叔胺。
Interfacial hydrogenation and deamination of nitriles to selectively synthesize tertiary amines.
作者信息
Lu Shuanglong, Li Chao, Wang Jiaqing, Pan Yue, Cao Xueqing, Gu Hongwei
机构信息
Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Science & Collaborative Innovation Center of Suzhou Nano Science and Technology, Soochow University, Suzhou, 215123, China.
出版信息
Chem Commun (Camb). 2014 Oct 4;50(76):11110-3. doi: 10.1039/c4cc05132g.
A novel one-pot method has been developed for the interfacial hydrogenation of nitriles to synthesize asymmetrical tertiary amines. The active Pt NWs allow for the preparation of a series of tertiary amines in excellent yields (up to 99.0%) and a mixed solvent is vital for the adjustment of the yield. And also, the reaction proceeded under mild conditions and is environmentally friendly.
一种用于腈的界面氢化以合成不对称叔胺的新型一锅法已被开发出来。活性铂纳米线能够以优异的产率（高达99.0%）制备一系列叔胺，并且混合溶剂对于产率的调节至关重要。此外，该反应在温和条件下进行且环境友好。
Zotero 插件