氮掺杂一维（1D）大孔碳纳米管阵列及其在电催化氧还原反应中的应用。
Nitrogen-doped one-dimensional (1D) macroporous carbonaceous nanotube arrays and their application in electrocatalytic oxygen reduction reactions.
机构信息
Collaborative Innovation Centre for Marine Biomass Fibers, Materials and Textiles of Shandong Province, College of Chemical and Environmental Engineering, Qingdao University, Qingdao, PR China.
出版信息
Nanoscale. 2014 Oct 7;6(19):11057-61. doi: 10.1039/c4nr03340j.
A nitrogen(N)-doped one-dimensional (1D) macroporous carbonaceous nanotube array was fabricated by using an anodic alumina oxide (AAO) template. The large diameter of the nanotubes (∼200 nm) could overcome the sluggish mass transfer phenomena in the common micro/mesoporous carbon-based electrodes. Combining the activation of the π electrons of the sp(2) carbon array by N-doping, the novel 1D macroporous carbonaceous nanotube array exhibited high performance for the oxygen reduction reaction (ORR).
采用阳极氧化铝模板（AAO）制备了一种氮（N）掺杂的一维（1D）大孔碳纳米管阵列。纳米管的大直径（~200nm）克服了常见的微/介孔碳基电极中缓慢的传质现象。通过 N 掺杂对 sp(2) 碳阵列的π电子进行活化，新型 1D 大孔碳纳米管阵列在氧还原反应（ORR）中表现出了优异的性能。
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