硝酸（N-苯基硫脲-κS）双（三苯基膦-κP）银（I）
(N-Phenyl-thio-urea-κS)bis-(tri-phenylphosphane-κP)silver(I) nitrate.
作者信息
Mekarat Sofia, Pakawatchai Chaveng, Saithong Saowanit
机构信息
Faculty of Science and Technology, Princess of Naradhiwas University, Narathiwat, 96000, Thailand.
Department of Chemistry and Center of Excellence for Innovation in Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.
出版信息
Acta Crystallogr Sect E Struct Rep Online. 2014 Jun 25;70(Pt 7):m281-2. doi: 10.1107/S1600536814014147. eCollection 2014 Jul 1.
In the title salt, [Ag(C7H8N2S)(C18H15P)2]NO3, the coordination geometry about the Ag(I) atom is shallow trigonal pyramidal, with the metal atom displaced by 0.372 (1) Å from the plane of the P and S atoms. In the crystal, the cations are linked to the anions by N-H⋯O hydrogen bonds, generating tetra-mers (two cations and two anions), which feature R 2 (2)(8) and R 4 (4)(8) loops. The cations are linked by weak C-H⋯π inter-actions, generating a three-dimensional network.
在标题盐[Ag(C₇H₈N₂S)(C₁₈H₁₅P)₂]NO₃中，Ag(I)原子周围的配位几何形状为浅三角锥形，金属原子偏离P和S原子平面0.372(1) Å。在晶体中，阳离子通过N-H⋯O氢键与阴离子相连，形成四聚体（两个阳离子和两个阴离子），其具有R₂²(8)和R₄⁴(8)环。阳离子通过弱C-H⋯π相互作用相连，形成三维网络。
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