Wattanakanjana Yupa, Nimthong Arunpatcha, Darasuriyong Chanokphat
Department of Chemistry, Faculty of Science, Prince of Songkla University, Hat Yai, Songkhla 90112, Thailand.
Department of Chemistry, Youngstown State University, 1 University Plaza, 44555 Youngstown, OH, USA.
Acta Crystallogr Sect E Struct Rep Online. 2014 Aug 30;70(Pt 9):m337-8. doi: 10.1107/S1600536814019047. eCollection 2014 Sep 1.
In the mononuclear title salt, Ag(C3H8N2S)(C18H15P)3, the Ag(I) ion exhibits a distorted tetra-hedral coordination sphere defined by three P atoms from three tri-phenyl-phosphane ligands and one S atom from a 1,3-di--methyl-thio-urea ligand. In the crystal, the acetate anion is linked with the complex cation via duplex N-H⋯O hydrogen bonds [graph-set motif R (2) 2(8)].
在单核标题盐Ag(C₃H₈N₂S)(C₁₈H₁₅P)₃中，Ag(I)离子呈现出一个扭曲的四面体配位环境，由三个三苯基膦配体的三个P原子和一个1,3 - 二甲基硫脲配体的一个S原子界定。在晶体中，醋酸根阴离子通过双N - H⋯O氢键与络合阳离子相连[图式R (2) 2(8)]。
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