一种针对具有未配位氮杂原子位点的沸石四唑酸盐-咪唑酸盐骨架（ZTIFs）以实现高二氧化碳吸附量的新方法。
A new approach towards zeolitic tetrazolate-imidazolate frameworks (ZTIFs) with uncoordinated N-heteroatom sites for high CO2 uptake.
作者信息
Wang Fei, Fu Hong-Ru, Kang Yao, Zhang Jian
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
出版信息
Chem Commun (Camb). 2014 Oct 18;50(81):12065-8. doi: 10.1039/c4cc05022c.
PMID:25162794
Abstract
Successful development of a new synthetic approach towards zeolitic tetrazolate-imidazolate frameworks (ZTIFs) via combining tetrazolates into the zinc-imidazolate frameworks leads to new ZTIF materials (ZTIF-1 and ZTIF-2) with zeolite-type topologies and uncoordinated N-heteroatom sites, which exhibit high CO2 uptake capacity.
摘要
通过将四唑酸盐结合到锌-咪唑酸盐骨架中，成功开发出一种合成沸石型四唑酸盐-咪唑酸盐骨架（ZTIFs）的新方法，从而得到具有沸石型拓扑结构和未配位N-杂原子位点的新型ZTIF材料（ZTIF-1和ZTIF-2），这些材料表现出高二氧化碳吸附能力。
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