一种用于高效高选择性二氧化碳捕集的四面体咪唑骨架的新方法。

A new approach towards tetrahedral imidazolate frameworks for high and selective CO2 uptake.

机构信息

State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, PR China.

出版信息

Chem Commun (Camb). 2011 May 28;47(20):5828-30. doi: 10.1039/c1cc10829h. Epub 2011 Apr 12.

DOI:10.1039/c1cc10829h

PMID:21487610

Abstract

Successful development of a new synthetic approach towards tetrahedral imidazolate frameworks (TIFs) via combining an auxiliary uninegative linker into the zinc-imidazolate tetrahedral assembly leads to new TIF materials (TIF-A1 to TIF-A3) with distinct structural topologies and high CO(2) uptake capacity.

摘要

成功开发了一种新的四面体咪唑骨架（TIFs）合成方法，通过将辅助的单负配体连接到锌-咪唑四面体组装中，得到了具有独特结构拓扑和高 CO2 吸附容量的新型 TIF 材料（TIF-A1 至 TIF-A3）。