Deng Guodong, Zhang Yuanzhong, Ye Changhuai, Qiang Zhe, Stein Gila E, Cavicchi Kevin A, Vogt Bryan D
Department of Polymer Engineering, The University of Akon, Akron, OH 44325, USA.
Chem Commun (Camb). 2014 Oct 28;50(84):12684-7. doi: 10.1039/c4cc02471k.
Bicontinuous mesoporous carbon films are fabricated by cooperative self-assembly of phenolic resin and amphiphilic triblock copolymer via an order-order transition from cylinders to gyroid. The film morphology is strongly influenced by the details of processing, including age of the resol, resol : template ratio, and the solvent vapor annealing process.
通过酚醛树脂和两亲性三嵌段共聚物的协同自组装，经由从圆柱相到螺旋状的有序-有序转变，制备出了双连续介孔碳膜。膜的形态受到加工细节的强烈影响，这些细节包括甲阶酚醛树脂的老化程度、甲阶酚醛树脂与模板的比例以及溶剂蒸汽退火过程。
